Macroparticle generation in DC arc discharge from a WC cathode

We have studied macroparticle generation from a tungsten carbide (WC) cathode used in a dc vacuum arc discharge. Despite a relatively high decomposition/melting point (~ 3100 K), there is an intensive generation of visible particles with sizes in the range 20-35 μm. Visual observations during the discharge and scanning electron microscopy of the cathode surface as well as of collected macroparticles indicate a new mechanism for particle formation and acceleration. Based on the W-C phase diagram there is an intensive sublimation of carbon from the melt resulting from the cathode spot. The sublimation supports the formation of a sphere, which is accelerated upon an explosion initiated by Joule heating at the critical contact area between the sphere and the cathode body. The explosive nature of the particle acceleration is confirmed by surface features resembling the remains of a splash on the droplet surface. aCorresponding author: [email protected], phone +46 730 52 10 12, fax +46 13 137568